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Chemistry 101

Week 6: Gases

Introduction to Gases

In this lesson, we will explore the properties of gases and the laws that govern their behavior. We will cover the following topics:

Kinetic Molecular Theory

The Kinetic Molecular Theory (KMT) is a model that helps explain the behavior of gases. According to KMT, gases consist of particles (molecules or atoms) that are in constant, random motion. The key postulates of KMT are:

  1. Gas particles are in constant, random motion.
  2. Gas particles have negligible volume compared to the space between them.
  3. Gas particles have no attractive or repulsive forces between them.
  4. The average kinetic energy of gas particles is proportional to the absolute temperature.

Pressure

Pressure is the force exerted by gas particles per unit area. It is measured in units such as atmospheres (atm), pascals (Pa), or millimeters of mercury (mmHg). The pressure of a gas depends on the number of particles, the temperature, and the volume of the container.

Gas Laws

The behavior of gases can be described by several laws that relate pressure, volume, temperature, and amount of gas. These laws are empirical relationships based on experimental observations.

Boyle's Law

Boyle's Law states that the pressure and volume of a fixed amount of gas at constant temperature are inversely proportional. Mathematically, P₁V₁ = P₂V₂, where P is pressure, V is volume, and the subscripts 1 and 2 represent two different states.

Charles's Law

Charles's Law states that the volume of a fixed amount of gas at constant pressure is directly proportional to its absolute temperature. Mathematically, V₁/T₁ = V₂/T₂, where V is volume, T is absolute temperature, and the subscripts 1 and 2 represent two different states.

Gay-Lussac's Law

Gay-Lussac's Law states that the pressure of a fixed amount of gas at constant volume is directly proportional to its absolute temperature. Mathematically, P₁/T₁ = P₂/T₂, where P is pressure, T is absolute temperature, and the subscripts 1 and 2 represent two different states.

Ideal Gas Law

The Ideal Gas Law combines the relationships between pressure, volume, temperature, and amount of gas into a single equation: PV = nRT, where P is pressure, V is volume, n is the number of moles of gas, R is the ideal gas constant (8.314 J/mol·K), and T is absolute temperature.

In the next section, we will apply these concepts to solve problems related to gases.